Turns out Chromecast with Google TV 4K is a Matter controller now
The Chromecast with Google TV 4K received time ago Google Home controls but back then it was not a Matter controller, i.e. was not a "hub for Google Home" like the Google Streamer. It is not listed either on the official list of hubs for Google Home.
(Don't confuse it with Thread border router, only the Streamer has that feature since the Chromecast has no Thread radio)
I might have missed an announcement, but turns out my CCwGTV 4K IS a Matter controller now.
The realization came wanting to test what happened when adding a device without a Matter controller / hub available. I added a Matter light fine (expected since the app does the onboarding) but, more surprisingly, was able to control it (unexpected).
At first I thought that maybe Google Home app finally added Matter controller features to use without hub like Apple Home or Smart Life apps do, this would have been such a killer feature!
Then I thought, could it be the Chromecast? And, yeah, I unplugged the Chromecast and the light went offline in Google Home. I plugged the Chromecast later, and the light went back online. Confirmed.