
The E in PETG stands for Glycol, not the G - description on prusament.com is wrong? Where are the chemists?
Hello there,
I stumbled upon this paragraph and it left me a bit confused, since my basic chemistry knowledge taught me otherwise.
>The G in the acronym PETG stands for Glycol which is added during the manufacturing process. Glycol modifies the properties of PET [...]
https://prusament.com/materials/prusament-petg/
To my understanding, the "G" in PETG does not simply stand for glycol, as is often claimed (and not just by Prusa). As confusing as this may sound, the "E" already stands for glycol - while the “G” actually stands for "glycol-modified copolyester" (and not "contains glycol").
Stick with me for a moment and let's start simple with good old PET.
PET stands for Poly Ethylene Terephthalate. It is produced from the monomers ethylene glycol and terephthalic acid (or dimethyl terephthalate). So the "E" effectively refers to ethylene glycol (also called monoethylene glycol or MEG). Since the common name for this substance is simply "glycol", the "E" already indirectly represents glycol. Chemists may also refer to the broader family of MEG-derived compounds collectively as "glycols".
Now to PETG. The common explanation is that glycol is "added during the manufacturing process". But that is not really what happens. Instead, part of the ethylene glycol is replaced with another diol - most commonly CHDM (cyclohexanedimethanol).
If the ratio of MEG to CHDM shifts further toward CHDM, the polymer may then be classified as PCTG, which some people might know as the "bigger, stronger brother" of PETG.
And finally, if the ethylene glycol were entirely replaced by CHDM, the result would essentially be PCT, yet another polyester.
Since I’m not a chemist, I’d genuinely appreciate feedback from someone with an actual background in polymer science to shed some more light on this - and, of course, correct me if I'm wrong.
TL;DR:
PCTG is a modified version of PCT with partially added (ethylene) glycol - but PETG is a modified version of PET with partially replaced (ethylene) glycol (or respectively, the G stands for "modified by an additional glycol / diol component").
Am i wrong?